The Journal of Organic Chemistry

A facile synthesis of two types of pyrrole-fused azacoronene with planar and double-concave π-structures was achieved. The two electron-rich azacoronenes were found to interact with electron-deficient π-electron compounds depending on their three-dimensional structures. Azacoronene with a curved structure was found to be less aromatic than those with a planar one based on macrocyclic π-conjugation.