The Journal of Organic Chemistry

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π-Extended Azacoronene with a Janus Double-Concave Structure
27 Apr 2021
A facile synthesis of two types of pyrrole-fused azacoronene with planar and double-concave π-structures was achieved. The two electron-rich azacoronenes were found to interact with electron-deficient π-electron compounds depending on their three-dimensional structures. Azacoronene with a curved structure was found to be less aromatic than those with a planar one based on macrocyclic π-conjugation.

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