Coordination Chemistry Reviews

Rie Makiura, Associate Professor at the Graduate School of Engineering, Osaka Metropolitan University has published a review article on the facile synthesis of nanosheet materials with precise regular nanoscale pores. In 2010, Professor Makiura’s research group succeeded in fabricating the world's first MOF (metal-organic framework) nanosheets on the surface of water using a simple low-energy process. The procedure, which involved adding drops of suitably chosen molecular components to the water surface took advantage of the same phenomenon that causes the formation of oil films and led to the creation of nanosheets of exceptional integrity and stability. In the present review article, Professor Makiura describes the MOF nanosheets developed by her group so far and provides a detailed description of their characteristics and comparison with other MOF nanosheets reported around the world. In addition, she describes the formation mechanism of the MOF nanosheets on the water surface.