Chemistry

Hydrogen fuel cells made with coordination polymer glass membranes could produce as much energy as their liquid-based counterparts while adding strength and flexibility.

Insights into a flipping crystal could further research into the development of autonomous robots.

Open access chemistry database PubChem will now include thousands of links to chemical and physical properties of materials from the SpringerMaterials database

Researchers at Kanazawa University and Tsukuba University report in Nanoscale that the physical properties of extracellular bacterial membrane vesicles are significantly diverse. The properties for a single type of bacterium as well as for different types are found to be highly heterogeneous.

A joint research group at Osaka City University and Sakai Chemical Industry Co., Ltd. have succeeded to synthesize black phosphorus with one-pot solvothermal reaction with red phosphorus in ethylenediamine used as a solvent.

A new technique allows researchers to test how the deformation of tiny train track-like cell proteins affects their function. The findings could help clarify the roles of deformed “microtubules” in traumatic brain injuries and in neurological diseases like Parkinson’s.

The remaining “bound water” on cotton surfaces cross-link single fibers of cotton, causing hardening after natural drying, according to a new study conducted by Kao Corporation and Hokkaido University. This provides new insight into unique water behaviors on material surfaces and helps us develop better cleaning technologies.

Physicists have been trying to observe the quantum phenomenon Kondo cloud for many decades. An international research team has recently developed a novel device that successfully measures the length of the Kondo cloud and even allows for controlling the Kondo cloud. The findings can be regarded as a milestone in condensed matter physics and may provide insights for understanding the multiple impurity systems, such as high-temperature superconductors.

A recent study, affiliated with South Korea's Ulsan National Institute of Science and Technology (UNIST) has introduced a new composite catalyst that could efficiently enhance the charg-discharge performances when applied to metal-air batteries (MABs),

Two faculty members from South Korea's Ulsan National Institute of Science and Technology (UNIST) have been honored with meritorious citations and awards for their outstanding research performance.

Molecular changes could improve the efficiency of next-generation photovoltaics.

South Korea's Ulsan National Institute of Science and Technology (UNIST) has signed a Memorandum of Understanding (MoU) with the Jeju Free International City Development Center (JDC) for research collaboration.

A recent study, affiliated with South Korea's Ulsan National Institute of Science and Technology (UNIST) has demonstrated bipolar all‐solid‐state Li–S batteries (ASSLSBs) that exhibit exceptional safety, flexibility, and aesthetics, for the first time.

A recent study, affiliated with South Korea's Ulsan National Institute of Science and Technology (UNIST) has unveiled a novel biomass conversion technology that can turn forestry biomass residues (i.e., sawdust from timber logging) into higher value fuels and chemicals.

Generating electricity from raindrops efficiently has gone one step further. A research team led by scientists from the City University of Hong Kong (CityU) has recently developed a droplet-based electricity generator (DEG), featured with a field-effect transistor (FET)-like structure that allows for high energy-conversion efficiency and instantaneous power density increased by thousands times compared to its counterparts without FET-like structure. This would help to advance scientific research of water energy generation and tackle the energy crisis.

Pressing issues in science and technology, including in healthcare and climate change, took centre-stage at the recent Global Young Scientists Summit 2020 where eminent scientists and talented young researchers worldwide convened in Singapore.

A biodegradable biopolymer containing turmeric oil could help extend food shelf life.

A new method could speed up drug discovery and lead to purer, side-effect-free medications.

A material aims to deliver a one-two punch: recycling atmospheric carbon dioxide for the production of more sustainable hydrocarbon fuels.

A low-cost catalyst on a sulphur-doped, porous, carbon nanostructure improves the performance of lithium batteries that run on air.

Researchers at Kanazawa University report in Analytical Chemistry an efficient method for filling a batch of nanopipettes with a pore opening below 10 nanometer. The method is based on the application of a temperature gradient to the nanopipette tips so that residual air bubbles are driven out.

A research team, affiliated with South Korea's Ulsan National Institute of Science and Technology (UNIST) has unveiled a novel algorithm that identifies optimal pairs for composing metal-organic frameworks (MOFs).

Researchers have shown mechanical force can start chemical reactions, making them cheaper, more broadly applicable, and more environmentally friendly than conventional methods.

Researchers at Tohoku University have discovered a way to detect carbon impurity in nitride semiconductors using light.

Two new Pd-based initiating systems for C1 polymerization of diazoacetates were reported: Pd(nq)2/borate (nq = naphthoquinone, borate = NaBPh4) and [Pd(cod)(Cl-nq)Cl/borate] [cod = 1,5-cyclooctadiene, Cl-nq = 2,3-dichloro-1,4-naphthoquinone]. The former exhibited high activity, affording poly(alkoxycarbonylmethylene)s with high molecular weights in high yields. The latter was effective for controlling the stereostructure of the resulting polymers.

Nitrogen-embedded polycyclic compounds with strong antiaromaticity and stability were synthesized and isolated for the first time using pyrrole as a key unit. An expedited approach toward stable antiaromatic polycyclic compounds enables not only the revealing of its fundamental properties, but also its application to organic electronic materials.

A research team of Ehime University paved a way to achieve unexplored III-V semiconductor nanostructures. They grew branched GaAs nanowires with a nontoxic Bi element employing characteristic structural modifications correlated with metallic droplets, as well as crystalline defects and orientations. The finding provides a rational design concept for the creation of semiconductor nanostructures with the concentration of constituents beyond the fundamental limit, making it potentially applicable to novel efficient near-infrared devices and quantum electronics.

Polycyclic heteroaromatic molecules are a highly useful class of organic materials. In this study, synthesis of a new azacoronene, in which both pyrrole and azulene moieties are circularly fused, was achieved in just three steps. This new azacoronene exhibited multistep reversible oxidations under electrochemical and chemical conditions. Formation of an aromatic 22π-electron conjugation and a tropylium cation (6π-electron conjugation) in the dicationic state played a key role in stabilizing this cationic species.

The captured CO2 can be converted into useful organic materials.

A new type of degradable synthetic polymer was prepared by Rh-catalyzed three-component polymerization of a bis(diazocarbonyl) compound, bis(1,3-diketone), and tetrahydrofuran. The resulting polymer, poly(β-keto enol ether), was highly sensitive to mild acidic conditions and degraded into a combination of well-defined low molecular weight compounds. With this unique degradability, the polymer could be utilized as an environmentally friendly polymeric material.