Chemistry

Researchers at Kanazawa University report in Science Advances how they can accelerate and decelerate chirality inversion in large cage molecules using alkali metal ion binding.

Glass is a fundamental material. Yet its atomic structure still baffles scientists to this day. Researchers have developed a new way to quantify ring shapes in chemically bonded networks of glass, chipping away at some of the mysteries behind glass’s atomic structure.

This paper highlights the underexplored potential of chiral self-sorting in the design of switchable and metastable discrete supramolecular structures.

Researchers at Kanazawa University report in Nature Communications how they can control chirality inversion in α helical peptides.

Lithium-oxygen batteries utilize oxygen in the surrounding air to generate energy. They have shown a high degree of theoretical potential, but the technology has stymied due to the specially designed carbon cathodes lacking certain characteristics. Researchers have made a breakthrough in this regard, developing a special type of porous carbon sheet called graphene mesoponge sheets.

Osaka Metropolitan University researchers have successfully synthesized ligands called fluorinated N-heterocyclic carbenes (NHCs) from environmentally harmful perfluoroalkenes, a type of synthetic chemicals also referred to as PFAS. These NHCs are valuable for stabilizing unstable molecules and enhancing catalytic efficiency. Through further structural modification, these NHCs are expected to find applications in a wide range of substances, including catalysts and light-emitting materials.

They say two heads are better than one. But in the world of fish, it appears two fins are better than one. Researchers have produced a theoretical model that demonstrates the underlying mechanisms behind how fish will synchronize their fin movements to ride each other’s vortices, thereby saving energy.

- A research team led by Professor Jong-min Choi at the Department of Energy Science and Engineering, DGIST, collaborated with a research team of Professor Bum-joon Kim’s research team at the Department of Chemical and Biomolecular Engineering, KAIST, to develop bipolar polymers, which can improve the efficiency and stability of perovskite solar cells - Developed a process that can repair defects and maximize multifunctionality with the double introduction of bipolar polymers

A research team at Osaka Metropolitan University has developed a new simulation method that accurately predicts powder mixing using AI, and has succeeded in increasing calculation speed by approximately 350 times while maintaining the same level of accuracy as conventional methods. This method is expected to not only pave the way for more efficient and precise powder mixing processes but also open up new possibilities for industries seeking to enhance product quality and streamline production.

- A research team led by Professor Jong-min Choi at the Department of Energy Science and Engineering, DGIST, has successfully developed stable quantum dot thin films, which can improve efficiency and stability in perovskite quantum dot solar cells. - Suggests a new quantum dot surface stabilization strategy based on a non-polar solvent and covalent ligands

- This team developed the PAINT technology that controls the adhesive properties of new organic materials, analyzes melanin formation processes, and facilitates selective melanin formation. - A research paper on the technology, which fabricates local patterns based on melanin-like pigments, was published in Nature Communications, an international academic journal.

Layered lithium cobalt oxide, a key component of lithium-ion batteries, has been synthesized at temperatures as low as 300°C and durations as short as 30 minutes.

A huge step forward in the evolution of perovskite solar cells recorded by researchers at City University of Hong Kong (CityU) will have significant implications for renewable energy development. The CityU innovation paves the way for commercialising perovskite solar cells, bringing us closer to an energy-efficient future powered by sustainable sources.

A research team from Osaka Metropolitan University has found that polysulfides are abundant in broccoli sprouts. They found that the amount of polysulfides increased dramatically during growth, by an approximately 20-fold in seeds by the fifth day of germination. Furthermore, a comprehensive analysis of the polysulfides detected a number of polysulfide candidates whose structures have not yet been determined. The identification of these unknown polysulfides and detailed analysis of their pharmacological activities are expected to enable the development of new preventive and therapeutic strategies and medicines for cancer, neurodegenerative diseases, stroke, inflammation, and other diseases.

Scientists have theoretically predicted that light can be bent under pseudogravity. A recent study by researchers using photonic crystals has demonstrated this phenomenon. This breakthrough has significant implications for optics, materials science, and the development of 6G communications.

The latest ‘large language model’ artificial intelligence system, GPT-4, could aid chemistry researchers, but limitations reveal the need for improvements.

Chemotherapy for cancer treatment often results in collateral damage to healthy cells and other adverse effects. A research team led by City University of Hong Kong (CityU) recently developed “sono-sensitised chemotherapy” (SSCT), a new form of ultrasound-activated chemotherapy, which further enhances the precision for eradicating deeper tumours with centimetre range of tissue penetration and minimises side effects.

Researchers from the Institute of Industrial Science, The University of Tokyo, synthesize a two-center zinc complex that absorbs visible light as a solid and in solution.

Friction, an everyday phenomenon, has perplexed scientists for centuries. Though extensively researched, our　understanding remains fragmented, primarily due to the multifaceted interactions that span across varying scales.　Achieving an accurate grasp of the precise contact conditions between objects has been a longstanding challenge, a feat recently made possible through advancements in scanning probe microscopy.

The behavior of electrons in liquids is crucial to understanding many chemical processes that occur in our world. Using advanced lasers that operate at the attosecond, a team of international researchers has revealed further insights into how electrons behave in liquids.

Researchers at Osaka Metropolitan University have succeeded in printing uniformly sized droplets with a diameter of approximately 100 µm using a liquid film of fluorescent ink. This ink, with a viscosity roughly 100 times that of water, was irradiated with an optical vortex, resulting in prints of exceptional positional accuracy at the micrometer scale.

Concave, umbrella-like metal complexes provide space to enable the largest molecular rotor operational in the solid-state.

An international group of researchers have proposed a new mechanism to enhance short-wavelength light (100-300 nm) by second harmonic generation (SHG) in a two-dimensional, thin material composed entirely of commonplace elements.

A group of researchers have unraveled the mysteries behind a recently identified material—zirconium nitride (ZrN) —that helps power clean energy reactions. Their proposed framework will help future designs for transition metal nitrides, paving a path for generating cleaner energy.

A recent discovery in spintronics could potentially transform future electronics. A group of researchers have revealed the key role of cobalt-tin-sulfur in reducing energy consumption, unlocking new possibilities for high-speed, low-power spintronic devices.

A team led by researchers at SANKEN (The Institute of Scientific and Industrial Research), at Osaka University has used neutron crystallography to image all of the atoms in a radical intermediate of a copper amine oxidase enzyme. They disclosed previously unknown details, such as precise conformational changes, that help to explain the enzyme's biochemistry. This work might help researchers engineer enzymes that facilitate unusual chemistry or are highly efficient at room temperature that are useful in chemical industry.

- Research team led by Professor Hongkyung Lee at DGIST developed a manufacturing process for high-quality thin film lithium cathode based on electroplating that can replace commercial lithium foil - Expected to improve battery life and replace existing lithium foil due to simple size enlargement

- DGIST-ETRI joint research team developed high-energy-density, high-stability all-solid-state battery electrode by applying the prelithiation technology to graphite-silicon electrodes - Selected as the back cover study by “Advanced Energy Materials,” the best international academic journal in energy

Lab-based studies reveal how carbon atoms diffuse on the surface of interstellar ice grains to form complex organic compounds, crucial to reveal the chemical complexity in the universe.

- Team led by Professor In Soo-Il at DGIST develops a titanium dioxide photocatalyst with enhanced optical and electrical properties utilizing silver and ruthenium - 135-fold increase in methane production compared to conventional TiO2 photocatalysts (95% selectivity proven)