Chemistry

Hokkaido University researchers find a new way of producing the industrially important propylene that is more energy efficient than existing approaches—and in the process turns carbon dioxide into another usable resource. Their pioneering catalyst design thus contributes to the carbon neutralization of the petrochemical industry.

Researchers found a new way to reduce carbon dioxide (CO2) emissions by wrapping copper nanocubes with an organic layer, solving instability and selectivity problems with copper nanocubes in catalysis, and improving how this electrocatalyst converts CO2 into organic molecules.

Researchers at The University of Tokyo create a geometric representation of thermodynamic systems and apply it to self-replicating processes, which may help improve our understanding of the physical constraints of living organisms

The research team directed by H. Shimomoto and E. Ihara in Ehime University successfully developed a new Pd-based initiating system affording carbon–carbon main-chain polymers bearing end-functional groups. This achievement will contribute to progress in the field of polymer chemistry and will allow us to develop new types of functional polymers.

Osaka Metropolitan University scientists developed a simple, rapid method for identifying food poisoning-inducing bacteria based on color differences in the scattered light of composite structures consisting of gold, silver, and copper nanoparticles and polymer particles. Using these composites as test labels bound to specific bacteria, the researchers detected food poisoning bacteria E. coli O26, E. coli O157, and S. aureus as white, red, and blue scattered light, respectively, under the microscope. This new method enables simultaneous identification of multiple bacterial species within one hour, significantly shortening the usual 48-hour time requirement for conventional bacterial tests.

Tohoku University scientists in Japan have developed a mathematical description of what happens within tiny magnets as they fluctuate between states when an electric current and magnetic field are applied. Their findings, published in the journal Nature Communications, could act as the foundation for engineering more advanced computers that can quantify uncertainty while interpreting complex data.

Researchers have made perovskite solar cells more efficient and stable, A new cause of Parkinson's related cell death, Hibernating superpower is in the blood, Common mechanism for cancer and atherosclerosis, COVID-19 antibody skin-based test. Read all in the August's Editor's Choice plus an Interview with Prof Sutee Yoksan on The story behind the new dengue vaccine & this month's Asia Research News 2022 magazine pick - The evolutionary history of puddle frogs.

Two new approaches could help scientists use existing sequencing technology to better-distinguish RNA changes that affect how their genetic code is read.

Osaka Metropolitan University researchers have successfully synthesized fumarate (fumaric acid), a raw material for unsaturated polyester resin, by combining carbon dioxide (CO2) with pyruvate (derived from biomass), using two biocatalysts: malate dehydrogenase and fumarase. Fumarate is currently used to make biodegradable plastic like polybutylene succinate from petroleum. However, this research has enabled the synthesis of fumarate without petroleum, consuming only CO2 and biomass-derived pyruvate.

A research group led by Professor Akitoshi Hayashi at the Osaka Metropolitan University Graduate School of Engineering has successfully developed a high-capacity capacitor, an energy storage device—using a solid electrolyte with high deformability—that can operate at high temperatures. With this discovery, high-capacity capacitors can now be made which do not require cooling, this increases their efficiency and allows for new suitable applications.

The flash of lightning and the dance of auroras contain a fourth state of matter known as plasma, which researchers have harnessed to produce a gas that may activate plant immunity against wide-spread diseases. The team, based at Tohoku University in Japan, published their findings on June 24 in PLOS One.

- Joint research team of DGIST and Korea Institute of Industrial Technology developed the first technology that removes microplastics in water through triboelectric nanogenerator - Expected to solve the problem of various microtoxic particles in water including microplastics, which have emerged as a huge environmental concern

- Clarified the relationship between the form of piezoelectric fiber components and their piezoelectric performance - Accelerated commercialization of energy harvesting textile materials that can recycle energy wasted or consumed in everyday life

Researchers at Kanazawa University report in Communications Biology that using common chemicals for fixing living cell samples for microscopy studies causes membrane proteins to aggregate.

Reaction design framework proposed by computations leads to the discovery of a wealth of reactions, opening new paths for drug development.

Researchers at Kanazawa University report in ACS Nano the development of a nanoparticle that acts as a heater and a thermometer. Inserting the nanoparticle in living cells results in a heat spot that, by switching it on and off, enables the controlled modulation of local cellular activities.

Scientists from the Institute of Industrial Science, The University of Tokyo, demonstrate that accounting for liquid preordering is essential to predicting crystal growth

New, easily fabricated, high performance carbon microlattice electrodes could soon be used to make cheaper batteries powered by readily available sodium ions. The approach was published by Tohoku University researchers and colleagues in the journal Small.

Osaka Metropolitan University researchers have clarified the first suitable computational conditions for Adiabatic State Preparation (ASP) executable on a quantum computer, a method that can improve the accuracy of calculating atomic and molecular wave functions. ASP is thought to be one of the leading methods for efficiently preparing correlated wave functions of molecules with complex electronic structures, but the specific conditions required for the calculations have not been thoroughly investigated so far. This new research has clarified the computational conditions needed to use ASP, a major development for making quantum chemical calculations on a quantum computer practical for chemical or materials research.

Evidence for Molecular Packing of Monovalent Iridium (III) Complexes within Interlayer Spaces of Sodium Montmorillonite

Nonthermal plasma (NTP) is used to activate CO2 molecules for hydrogenation into alternative fuels at low temperatures, also enabling the conversion of renewable electricity to chemical energy. Researchers from Tokyo Tech combined experimental and computational methods to investigate the hydrogenation pathway of NTP-promoted CO2 on the surface of Pd2Ga/SiO2 catalysts. The mechanistic insights from their study can help improve the efficiency of catalytic hydrogenation of CO2 and allows the engineers to design new concept catalysts.

Solar panels often get a bad rap for spoiling the appearance of homes and businesses. Yet, a research group has fabricated a highly transparent solar cell with a 2D atomic sheet. These near-invisible solar cells achieved an average visible transparency of 79%, meaning they can, in theory, be placed everywhere—building windows, the front panel of cars, and even human skin.

A research team co-led by chemists from City University of Hong Kong (CityU) and Imperial College London (Imperial College) has developed new, highly efficient and stable perovskite solar cells. The breakthrough invention is expected to greatly accelerate the commercialisation of perovskite photovoltaic technology, providing a promising alternative to silicon solar cells.

A thermoelectric metal oxide film with a thermoelectric figure of merit of ~0.55 at 600°C has been discovered, opening new avenues towards the widespread use of thermoelectric converters.

Researchers at Kanazawa University report in The Journal of Physical Chemistry Letters how to simulate 3D atomic force microscopy images of out-of-equilibrium systems involving biomolecules. The approach makes use of a celebrated equation from thermodynamics applicable to non-equilibrium situations.

Researchers from the Institute of Industrial Science, The University of Tokyo, find that organic vapors can induce dissolution of molecular salts (i.e., organic deliquescence), similar to water vapor-induced deliquescence

Rie Makiura, Associate Professor at the Graduate School of Engineering, Osaka Metropolitan University has published a review article on the facile synthesis of nanosheet materials with precise regular nanoscale pores. In 2010, Professor Makiura’s research group succeeded in fabricating the world's first MOF (metal-organic framework) nanosheets on the surface of water using a simple low-energy process. The procedure, which involved adding drops of suitably chosen molecular components to the water surface took advantage of the same phenomenon that causes the formation of oil films and led to the creation of nanosheets of exceptional integrity and stability. In the present review article, Professor Makiura describes the MOF nanosheets developed by her group so far and provides a detailed description of their characteristics and comparison with other MOF nanosheets reported around the world. In addition, she describes the formation mechanism of the MOF nanosheets on the water surface.

New dinosaur species used claws to graze along the coast, More accurate rainfall predictions, Magnetism helps futuristic cell research, Do compression garments facilitate muscle recovery? Science journalism and why it matters for democracy and our Image of the month. Read all in the June's Editor's Choice and this month's Asia Research News 2022 magazine pick - Lessons from the dead.

Atomic force microscopy (AFM) allows to visualize the dynamics of single biomolecules during their functional activity. All observations are, however, restricted to regions accessible by a fairly big probing tip during scanning. Hence, AFM images only the biomolecular surface with limited spatial resolution, missing important information required for a detailed understanding of the observed phenomena.

The molecule is unusual and has ‘great potential’ in catalysis, conduction and other applications.