Physics Molecular physics
17 Jun 2022
A research group led by Professor Yoshio Teki of the Osaka Metropolitan University Graduate School of Engineering has succeeded in developing a new pentacene derivative that is more than 100 times more photostable than TIPS-pentacene, a photostable pentacene derivative. Additionally, the team has further clarified the ultrafast excited state dynamics in this system. In the pentacene moiety of this system, we were able to demonstrate that the transition from the excited singlet state to the excited triplet state occurs ultrafast in the time region of a 10-13 seconds. In purely organic materials without heavy atoms such as rare metals, such intersystem crossing usually occurs on time scales longer than 10-9 seconds. The empirical results of this study are expected to be applied as a method for stabilizing and developing light-unstable materials in the future.
06 Jun 2022
Researchers at the Institute of Industrial Science, The University of Tokyo studied the anomalous properties of amorphous solids, including glasses, using computer simulations, and found a common vibrational mechanism underlying them, which may help control the glass properties
16 May 2022
Researchers from the Osaka Metropolitan University Graduate School of Engineering have successfully developed a new technique allowing them to observe gas molecules packing into metal-organic frameworks (MOF) using infrared spectroscopy. Their innovation was to measure polarized light absorption of guest molecules in a MOF film to deduce molecule alignment using this common piece of lab equipment. This method is the first to show guest alignment and does so in real-time, while using an accessible and easily adoptable experimental setup. A short video (4 min) recreating their spectrometer modifications can be found in the Reference section.
28 Feb 2022
Scientists developed a procedure to reproduce the double peak feature of x-ray emission spectroscopy (XES) spectra in liquid water.
02 Sep 2021
Researchers at Kanazawa University report in Proceedings of the National Academy of Sciences how a protein molecular motor can chop off a piece of cell membrane. The constrict-and-cut mechanism resembles that of a ratchet motor, and is of importance in processes mediating the entry of particles into cells.
05 Jul 2021
Osaka Prefecture University develops a method to design and control the path of electron flow in a polycrystalline material. Using epitaxial growth approach, researchers address the electrical conductivity problem of thin film materials by realizing a highly conductive in-plane orientation of a metal-organic framework. Furthermore, they show that it is possible to fabricate oriented thin film patterns by integration with UV lithography technology.
17 Jun 2021
Researchers at Osaka Prefecture University have established an approach to identify the orientation of molecules and chemical bonds in crystalline organic-inorganic hybrid thin films deposited on substrates using Fourier transform infrared spectroscopy (FT-IR) and polarized infrared light with a 3D-printed attenuated total reflectance (ATR) unit. This inexpensive method with laboratory-grade equipment quickly reaches the crystal-structure model of even extremely thin films of less than 10 nm.
09 Jun 2021
Chemical rings of carbon and hydrogen atoms curve to form relatively stable structures capable of conducting electricity and more — but how do these curved systems change when new components are introduced? Researchers based in Japan found that, with just a few sub-atomic additions, the properties can pivot to vary system states and behaviors, as demonstrated through a new synthesized chemical compound.
10 Feb 2021
Researchers at The University of Tokyo discover a new law about how the complex network of phase-separated structures grows with time, which may lead to more efficient batteries and industrial catalysts
18 Jan 2021
Researchers at Osaka City University use quantum superposition states and Bayesian inference to create a quantum algorithm, easily executable on quantum computers, that accurately and directly calculates energy differences between the electronic ground and excited spin states of molecular systems in polynomial time.
29 Oct 2020
Scientists at The University of Tokyo use a two-state model based on the formation of tetrahedral structures to explain water’s anomalous properties and the surprising liquid–liquid transition of water.
13 Jul 2020
A hemispherical vanadium oxide cluster has a cavity that can accommodate a bromine molecule. It was found that a bromine molecule trapped in the cavity was polarized and that an alkane molecule like pentane, butane and propane could be brominated with the bromine molecule in the cavity with a selectivity differing from ordinary bromination. The present findings are expected to be useful for polarization of small molecules and design of highly functional catalysts.
17 Jun 2020
Professor Tetsuo Endoh, leading a group of researchers at Tohoku University, has announced the development of an MTJ (Magnetic Tunnel Junction) with 10 ns high-speed write operation, sufficient endurance (>10<sup>11</sup>), and with highly reliable data retention over 10 years at 1X nm size. Realizing a 1X nm STT-MRAM (Spin Transfer Torque-Magnetoresistive Random Access Memory) and NV(Non-Volatile)-Logic has wide application to a variety of fields.
07 Sep 2018
Researchers at Nagoya University, Japan, have developed a spontaneous polymer network synthesis that allowed for the preparation of gels containing narrow molecular weight distribution polymers. The gel networks showed swelling properties that were responsive to temperature and solvent concentration.
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