□ The joint research team of DGIST (President Kun Woo Lee) and Sogang University (Jong-hyeok Sim) has developed a new electrochemical catalyst that promotes the conversion from carbon dioxide (CO2) to ethylene (C2H4)[1]. Through joint efforts led by Professors Dae-hyun Nam and Youn-gu Lee from the Department of Energy Science and Engineering at DGIST and Professor Seo-in Back from the Department of Chemical and Biomolecular Engineering at Sogang University, the joint research team has devised a technology to substantially enhance ethylene production by incorporating “vitamin C” into a carbon dioxide reduction catalyst of a heterogeneous system[2]. This is based on the observation that the presence of carbon dioxide in the air impacts the “vitamin C” levels in fruits.
□ The electrochemical reduction of carbon dioxide is gaining recognition as a fundamental technology for “eco-friendly energy.” This process aims to decrease the concentration of carbon dioxide in the atmosphere while generating cleaner sources of future energy. However, existing electrochemical catalysts face challenges in achieving consistent catalytic performance under high current density conditions. This limitation hampers the formation of the essential intermediate product: carbon monoxide, which plays a critical role in ethylene conversion. Instead, these catalysts tend to induce the reaction for hydrogen generation rather than the carbon dioxide reduction reaction.
□ Therefore, for seamless reduction of carbon dioxide, it is significant to achieve stable formation of the intermediate product of carbon monoxide at high current density through an electrochemical catalyst, and to promote dimerization[3] where two carbon monoxide intermediate products are combined. Thus, the research team led by Professor Nam at DGIST devised a method to integrate the oxidation-reduction reaction[4] of vitamin C into the electrochemical reduction of carbon dioxide, based on the phenomenon where the vitamin C content in fruits decreases in an environment with a high concentration of carbon dioxide.
□ The research team synthesized vitamin C with graphene quantum dots, and fabricated a “vitamin C boosting copper nanowire” by combining the synthesized material with copper. This approach helped stabilize vitamin C through nano-confinement effects of graphene quantum dots, and enabled reversibility[5] of oxidation-reduction. Additionally, the oxidation-reduction reaction of vitamin C consistently supplied electrons and protons to carbon dioxide, promoting the dimerization process and creating the carbon monoxide intermediate product. Consequently, the newly developed catalyst exhibited a 2.9-fold enhancement in ethylene production compared to conventional copper nanowire catalysts.
□ Furthermore, the research team identified that the vitamin C confined in graphene optimizes the integration of carbon monoxide intermediate product and copper catalyst through real-time Raman spectroscopic analysis and computer simulation. Furthermore, the research team identified the working principle of the catalyst by verifying that electrons and protons can be delivered, which facilitates reduction reaction of carbon dioxide based on a strong hydrogen bond.
□ Professor Nam at DGIST stated, “This research created an electrochemical catalyst capable of large-scale ethylene production through the reduction of carbon dioxide and revealed a novel reaction mechanism.” He added, “This technology is expected to play a key role in achieving carbon neutrality by transforming carbon dioxide—a major contributor to global warming—into a high-value compound.”
□ This research was supported as part of the Excellent New Research Project by the National Research Foundation of Korea (NRF) under the Ministry of Science and ICT, and as Nano/Material Technology Development Project and Leading Research Center Support Project (Sustainable Utilization of Photovoltaic Energy Research Center). The findings were published in the January 2024 issue of the prestigious academic journal, “Nature Communications.”
- Ccorresponding Author E-mail Address : [email protected]
[1] Ethylene (C2H4): A plant hormone or a hydrocarbon characterized by a simple chemical structure, which triggers or regulates processes such as fruit maturation, flowering, or leaf abscission
[2] Heterogeneous system: A system comprising two or more phases (e.g., solid and gas or solid and liquid)
[3] Dimerization: Substance created by polymerization of two identical molecules
[4] Oxidation-reduction reaction: Simultaneous oxidation and reduction occur as electrons move between substances. The substance that loses an electron experiences oxidation, resulting in an increased oxidation number, while the substance that gains an electron undergoes reduction, leading to a decreased oxidation number. The number of lost and gained electrons is always the same.
[5] Reversibility: Property where the material can revert to its original state if the motion of the material undergoes a time reversa
